Hi guys,
Thanks for the welcome!
@Ian: I have left it for several hours at the "Starting Windows" screen. There does not appear to be any HDD activity. If I am attempting to boot from the DVD, the disc spins down and does not get accessed again until I reboot.
@ronpeck: Thanks for the advice. I need to make acronis backups, but I haven't got around to installing acronis on this PC, since I had some issues with it on my last machine. The acronis background service was hogging resources like crazy, so I killed it.

I'll keep searching I guess.
Any other ideas pop up, please don't hesitate to share them!
Elmojo