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I read that the professional version would allow more of the 32-bit drivers to work. Is that correct?
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No, 32 bit drivers will not work on an x64 OS. You must use x64 drivers.
There are no x64 drivers for the Canon LiDE 80 scanner in either Windows 7 or Vista or XP. Only x86 (32 bit) drivers. This seem to be fairly new scanner model, so you might try calling Canon Tech Support to see if and when they'll have 64 bit drivers for the scanner.
Good News... there are x64 Windows 7 drivers for your Canon PIXMA iP4000. You can download them
HERE.