If for some reason the key doesn't work during Install. Wait until after the Install and then you can Activate from the bottom of Computer Properties page.
Shortcut key to open Computer Properties is "Windows Key + Pause".
Scroll to the bottom it should say "Activate Windows Now" or "Windows is Activated".
If Windows has been deactivated for some reason, it may say something along the line of "You may be a victim of piracy". I have actually seen this before and going through activation again straighten things out.