How to play in other playback device?

I'd like to play to both device and I want to set different vol to them.
But now I can just play in speakers.
Alternatively, can I set different application to play in playback device individually ?

Hi - Welcome on the forums!
Ok, so your best shot is probably "Virtual Audio Cable". Here is the link:
www.software.muzychenko.net/eng/vac.html

By the way, where did you find that image?
Thanks to Core for the link.

Cheers,
Fire Cat

He probably used the Snipping tool which is a free application in Windows 7.

I use Snagit 10 because it has tons of features and different ways to save the files.