Make/model of the 2TB drives?
What do you mean they were not formatted - to be used they must be formatted so if they weren't formatted then they are empty. Or do you mean they have NOT been reformatted so the info should still be there? If that is what you mean then how were they originally formatted (NTFS, FAT32, ?)?
To be honest I have heard of problems going the other way, the 64-bit OS can see it but XP can't and that is usually caused because of the newer large 4K sectors. Read more
HERE. But I'm not sure how this could cause your issue.