Did you configure the new card to run in Crossfire in the Catalyst Control Center ? If you didn't right-click on your destop and click on Catalyst Control Center/AMD Vision Control Center. In Catalyst Control Center click on Performance on the left side, then click on Graphics Overdrive. You should see a listing for CrossfireX, make sure there's a check mark there. Then restart your computer and go into the bios and enable Crossfire there. Then go to
http://www.amd.com and download the 12.1 driver's and the Catalyst Profiles. Those were all just released this past Monday.