What kind of DL discs are these? Did you burn them yourself? El cheapo brand, or something better?
Let me ask you this: have you tried connecting the external drive to a different computer, inserting one of the discs that your 7 machine did not read at all, and seeing if the other computer, using the same external (or internal, if possible) drive can see it?
This might help determine whether the issue is with Windows, or with the media or the drives. While I've heard of both, the symptoms suggest a shot drive, but it's unusually unlucky that both drives would be going out at the same time, so I wouldn't rule out a software problem just yet.
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